Stainless Steel History Application Properties and Recycling & Reuse
Chemical Composition Chart Stainless Steel Pipe
History
A few corrosion-resistant iron artifacts survive from antiquity. A famous example is the Iron Pillar of Delhi, erected by order of Kumara Gupta I around the year AD 400. Unlike stainless steel, however, these artifacts owe their durability not to chromium, but to their high phosphorus content, which, together with favorable local weather conditions, promotes the formation of a solid protective passivation layer of iron oxides and phosphates, rather than the non-protective, cracked rust layer that develops on most ironwork.
The corrosion resistance of iron-chromium alloys was first recognized in 1821 by the French metallurgist Pierre Berthier, who noted their resistance against attack by some acids and suggested their use in cutlery. Metallurgists of the 19th century, however, were unable to produce the combination of low carbon and high chromium found in most modern stainless steel, and the high-chromium alloys they could produce were too brittle to be practical.
In the late 1890s, Hans Goldschmidt of Germany developed an aluminothermic process for producing carbon-free chromium.In the years 1904–1911 several researchers, particularly Leon Guillet of France, prepared alloys that would today be considered stainless steel.
Friedrich Krupp Germaniawerft built the 366-ton sailing yacht Germania featuring a chrome-nickel steel hull in Germany in 1908. In 1911, Philip Monnartz reported on the relationship between the chromium content and corrosion resistance. On October 17, 1912,Krupp engineers Benno Strauss and Eduard Maurer patented austenitic stainless steel.
Similar developments were taking place contemporaneously in the United States, where Christian Dantsizen and Frederick Becket were industrializing ferritic stainless steel. In 1912, Elwood Haynes applied for a U.S. patent on a martensitic stainless steel alloy. This patent was not granted until 1919
Also in 1912, Harry Brearley of the Brown-Firth research laboratory in Sheffield, England, while seeking a corrosion-resistant alloy for gun barrels, discovered and subsequently industrialized a martensitic stainless steel alloy. The discovery was announced two years later in a January 1915 newspaper article in The New York Times.Brearly applied for a U.S. patent during 1915. This was later marketed under the brand by Firth Vickers in England and was used for the new entrance canopy for the Savoy Hotel in 1929 in London.
Properties
High oxidation-resistance in air at ambient temperature are normally achieved with additions of a minimum of 13% (by weight)chromium,and up to 26% is used for harsh environments.The chromium forms a passivation layer of chromium(III) oxide(Cr2O3) when exposed to oxygen. The layer is too thin to be visible, and the metal remains lustrous. It is impervious to water and air, protecting the metal beneath. Also, this layer quickly reforms when the surface is scratched. This phenomenon is called passivation and is seen in other metals, such as aluminium and titanium. Corrosion resistance can however be adversely affected if the component is used in a non-oxygenated environment, a typical example being underwater keel-bolts buried in timber.
When stainless steel pipe parts such as nuts and bolts are forced together, the oxide layer can be scraped off causing the parts to weld together. When disassembled, the welded material may be torn and pitted, an effect that is known as galling. This destructive galling can be best avoided by the use of dissimilar materials, e.g. bronze to stainless steel, or even different types of stainless steels when metal-to-metal wear is a concern. In addition, Nitronic alloys (trademark of Armco, Inc.) reduce the tendency to gall through selective alloying with manganese and nitrogen.
Applications
Stainless steel’s resistance to corrosion and staining, low maintenance, relatively low cost, and familiar luster make it an ideal base material for a host of commercial applications. There are over 150 grades of stainless steel, of which fifteen are most common. The alloy is milled into coils, sheets, plates, bars, wire, and tubing to be used in cookware,cutlery, hardware, surgical instruments,major appliances, industrial equipment, and as an automotive and aerospace structural alloy and construction material in large buildings. Storage tanks and tankers used to transport orange juice and other food are often made of stainless steel, due to its corrosion resistance and antibacterial properties. This also influences its use in commercial kitchens and food processing plants, as it can be steam cleaned, sterilized, and does not need painting or application of other surface finishes.
Stainless steel is also used for jewellery and watches. The most common stainless steel alloy used for this is 316L. It can be re-finished by any jeweller and will not oxidize or turn black.
Some firearms incorporate stainless steel components as an alternative to blued or parkerized steel. Some handguns, such as the Smith & Wesson Model 60 and the Colt M1911 can be made entirely from stainless steel. This gives a high-luster finish similar in appearance to nickel plating; but, unlike plating, the finish is not subject to flaking, peeling, wear-off due to rubbing (as when repeatedly removed from a holster over the course of time), or rust when scratched.
Some automotive aftermarket parts manufacturers use stainless steel only for the making of short shifters, and Weighted Gear Knobs.
Recycling & reuse
Stainless steel such as stainless steel tubes 100% recyclable. An average stainless steel object is composed of about 60% recycled material of which ≈40% originates from end-of-life products and ≈60% comes from manufacturing processes.
| UNS# |
ALLOY |
C |
Mn |
Cr |
Mo |
Ni |
Fe |
Si |
P |
S |
Al |
Cu |
Zn |
OTHER |
| S30400 |
SST-304 |
.08 |
2 |
18-20 |
-- |
8-10.5 |
BAL |
1 |
.045 |
.03 |
-- |
-- |
-- |
-- |
| S30403 |
SST-304L |
.03 |
2 |
18-20 |
-- |
8-12 |
BAL |
1 |
.045 |
.03 |
-- |
-- |
-- |
-- |
| S31600 |
SST-316 |
.08 |
2 |
16-18 |
2-3 |
10-14 |
BAL |
1 |
.045 |
.03 |
-- |
-- |
-- |
-- |
| S31603 |
SST-316L |
.03 |
2 |
16-18 |
2-3 |
10-14 |
BAL |
1 |
.045 |
.03 |
-- |
-- |
-- |
-- |
| S32100 |
SST-321 |
.08 |
2 |
17-19 |
-- |
9-12 |
BAL |
1 |
.045 |
.03 |
-- |
-- |
-- |
Ti 5 x C Min. |
| N08330 |
SST-330 |
.08 |
2 |
17-20 |
-- |
34-37 |
BAL |
.75-1.5 |
.03 |
.03 |
-- |
1 |
-- |
-- |
| S34700 |
SST-347 |
.08 |
2 |
17-19 |
.75 |
9-13 |
BAL |
1 |
.045 |
.03% |
-- |
.50 |
-- |
-- |
| S41000 |
SST-410 |
.15 |
1 |
11.5-13.5 |
-- |
-- |
BAL |
1 |
.045 |
.03 |
-- |
-- |
-- |
-- |
| S43000 |
SST-430 |
.12 |
1 |
16-18 |
-- |
-- |
BAL |
1 |
.045 |
.03 |
-- |
-- |
-- |
-- |
304/304L- The most widely used of the stainless steels. Offers good corrosion resistance to many environments. Has good formability and
can be readily welded.
309 - Used in high temperature applications. High scale resistance. Corrosion resistance superior to 304. Resists corrosion
when welded.
316/316L - Better corrosion resistance as well as higher strength at elevated temperatures than 304. Often used for pumps, valves, chemical equipment and marine applications. Most popular of stainless steel tube
321- Have a higher resistance to intergranular corrosion, for some organic acids and inorganic acids (especially in the oxidative medium) has a good corrosion resistance
I. Austenitic - A family of alloys containing chromium and nickel (and manganese and nitrogen when nickel levels are reduced), generally built around the type 302 chemistry of 18% Cr, 8% Ni, and balance mostly Fe. These alloys are not hardenable by heat treatment.
II. Ferritic - This group of alloys generally containing only chromium, with the balance mostly Fe, are based upon the type 430 composition of 17% Cr. These alloys are somewhat less ductile than the austenitic types and again are not hardenable by heat treatment.
III. Martensitic - The members of this family of stainless steels may be hardened and tempered just like alloy steels. Their basic building block is type 410 which consists of 12% Cr, 0.12% C, and balance mostly Fe.
IV. Precipitation-Hardening - These alloys generally contain Cr and less than 8% Ni, with other elements in small amounts. As the name implies, they are hardenable by heat treatment.
V. Duplex - This is a stainless steel alloy group, or family, with two distinct microstructure phases -- ferrite and austenite. The Duplex alloys have greater resistance to chloride stress corrosion cracking and higher strength than the other austenitic or ferritic grades.
VI. Cast - The cas stainless steel, in general, are similar to the equivalent wrought alloys. Most of the cast alloys are direct derivatives of one of the wrought grades, as C-8 is the cast equivalent of wrought type 304. The C preceding a designation means that the alloy is primarily used for resistance to liquid corrosion. An H designation indicates high temperature applications.
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