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Corrosion

Acetic Acid Corrosion / CH3COOH Corrosion






Acetic acid is an organic acid and a common ingredient for the manufacturing of a wide range of chemicals and products. The chemical formula for acetic acid is CH3COOH, and it is also known as ethanoic acid. Acetic acid is a colorless liquid with a pungent, vinegar-like odor. In water-free conditions acetic acid is named Glacial Acetic Acid. Corrosive nature of glacial acetic acid at temperature higher than 120°C

At temperatures greater than 120C acetic acids become extremely corrosive and specialty materials are needed to contain it. Typically zirconium has been the material of choice since its corrosion resistance to glacial acetic acid is good.  While zirconium offers good corrosion resistance to acetic acid, corrosion resistance to acetic acid is superb at a cost that is at least 30% less expensive than zirconium.

Testing in Glacial Acetic Acid

The test solution was prepared using a reagent grade Glacial Acetic Acid. Three test vessels. consisting of new PTFE lined pressure vessels were used. Approximately 65 ml of test solution was poured into each PTFE vessel. One test specimen was placed in each of the three test vessels.

All of the test specimens were completely immersed in the Glacial Acetic Acid. The washer and the Ta specimen were suspended above the bottom of the PTFE vessels using PTFE string attached to a PTFE bracket. The test vessels were then sealed. The assembled test vessels were placed in a laboratory oven at 205°C for a period of six (6) weeks (1008 hours)

 Specimen  Corrsion Rate (mpy)
 Tantaline  Ni
Solid Ta <0.02
Zirconium 705   0.1

Stainless Steel for Acetic acid, CH3COOH
Conc. CH3COOH% 10  10  10  20 
Temp. °C 90 100
=BP
20 50 75 100
=BP
20 75 100
=BP
20
Grade or type of alloy:
Carbon steel 1 2 1 2 2 2 1 2 2 2
13Cr 0 1 1 2 2 2 1 2 2 1
304/304L 0 0 0 0 0 0 0 0 1 0
TP316/316L 0 0 0 0 0 0 0 0 0 0
18Cr13Ni3Mo/317L 0 0 0 0 0 0 0 0 0 0
17Cr14Ni4Mo / 1.4439 0 0 0 0 0 0 0 0 0 0
904L / N08904 0 0 0 0 0 0 0 0 0 0
Sanicro 28 0 0 0 0 0 0 0 0 0 0
254 SMO 0 0 0 0 0 0 0 0 0 0
654 SMO 0 0 0 0 0 0 0 0 0 0
SAF 2304 0 0 0 0 0 0 0 0 0 0
SAF 2205 0 0 0 0 0 0 0 0 0 0
SAF 2507 0 0 0 0 0 0 0 0 0 0
Titanium (CP Ti) 0 0 0 0 0 0 0 0 0 0

Symbol clarification

These corrosion tables use a number of symbols, having the following meanings:

Symbol Description
0 Corrosion rate less than 0.1 mm/year. The material is corrosion proof.
1 Corrosion rate 0.1—1.0 mm/year. The material is not corrosion proof, but useful in certain cases.
2 Corrosion rate over 1.0 mm/year. Serious corrosion. The material is not usable.
p, P Risk (severe risk) of pitting and crevice corrosion.
c, C Risk (Severe risk) of crevice corrosion. Used when there is a risk of localised corrosion only if crevices are present. Under more severe conditions, when there is also a risk of pitting corrosion, the symbols p or P are used instead.
s, S Risk (Severe risk) of stress corrosion cracking.
ig Risk of intergranular corrosion.
BP Boiling solution.
ND No data. (Used only where there are no actual data to estimate the risk of localised corrosion instead of p or s).



Selection of Stainless Steel fo Handling Sulphur Dioxide SO2 and Sulphur Trioxide SO3
Selection of Stainless Steel for Handling Phosphoric Acid H3PO4
Selection of Stainless Steel for Handling Hydrofluoric Acid HF
Selection of Stainless Steel for Handling Citric Acid C3H4OH (COOH)3
Selection of Stainless Steel for Handling Ammonia NH3
Selection of Stainless Steel for Handling Chlorine Cl2 and Chlorine Dioxide ClO2
Selection of Stainless Steels For Handling Hydrochloric Acid HCl
Selection of Stainless Steel for Handling Sulphuric Acid H2SO4
Selection Stainless Steel for Handling Sodium Hydroxide NaOH
Selection of stainless steels for handling acetic acid (CH3COOH)
Selection of stainless steels for handling sodium hypochlorite (NaOCl)
Selection of stainless steels for handling nitric acid (HNO3)
NACE MR 0175/ISO 15156 for Corrosion Resistant Alloys for Sulphide Service
Selection of stainless steels in water supply and waste water treatment

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